Gọi nFe = a (mol); nAl = b (mol)

=> 56a + 27b = 11 (1)

nH2 = 8,96/22,4 = 0,4 (mol)

PTHH: 

Fe + 2HCl -> FeCl2 + H2

a ---> 2a ---> a ---> a

2Al + 6HCl -> 2AlCl3 + 3H2

b ---> 1,5b ---> b ---> b

=> a + 1,5b = 0,4 (2)

Từ (1)(2) => a = 0,1 (mol); b = 0,15 (mol)

mFe = 0,1 . 56 = 5,6 (g)

mAl = 0,2 . 27 = 5,4 (g)

THAM KHẢO :
 

Fe + 2HCl -> FeCl₂ + H₂ (1)

a) 2Al + 6HCl -> 2AlCl₃ + 3H₂ (2)

Gọi khối lượng Fe là x(g) (0<x<11) => n_Fe = x/56 (mol)

Thì m_Al là 11-x(g) => n_Al = (11-x)/27 (mol)

n_H2 = 8,96/22,4 = 0,4 (mol)

Theo PT (1) ta có: n_H2 = n_Fe = x/56 (mol)

Theo PT (2) ta có: n_H2 = 3/2 n_Al = 3/2 . (11-x)/27 = (11-x)/18 (mol)

Theo đề bài, n_H2 thu được là 0,4(mol) nên ta có:

x/56 + (11-x)/18 = 0,4

<=> 18x +56(11-x) = 403,2

<=> x = 5,6 (g)

Do đó: m_Fe = 5,6(g) => n_Fe = 5,6/56 = 0,1 (mol)

m_Al = 11-5,6 = 5,4(g) => n_Al = 5,4/27 = 0,2 (mol)

a) $CaSO_3 + 2HCl \to CaCl_2 + SO_2 + H_2O$
b)

$n_{SO_2} = n_{CaSO_3} = \dfrac{12}{120} = 0,1(mol)$
$m_{SO_2} = 0,1.64 = 6,4(gam)$

c)

$n_{HCl} = 2n_{SO_2} = 0,2(mol)$
$\Rightarrow m_{dd\ HCl} = \dfrac{0,2.36,5}{14,6\%} = 50(gam)$

d)

$m_{dd\ sau\ pư} = m_{CaSO_3} + m_{dd\ HCl} - m_{SO_2} = 12 + 50 - 6,4 = 55,6(gam)$

$C\%_{CaCl_2} = \dfrac{0,1.111}{55,6}.100\% = 19,96\%$

Ta có: \(n_{CaSO_3}=\dfrac{12}{120}=0,1\left(mol\right)\)

a. PTHH: CaSO₃ + 2HCl ---> CaCl₂ + H₂O + SO₂

b. Theo PT: \(n_{SO_2}=n_{CaSO_3}=0,1\left(mol\right)\)

=> \(m_{SO_2}=0,1.64=6,4\left(g\right)\)

c. Theo PT: \(n_{HCl}=2.n_{CaSO_3}=2.0,1=0,2\left(mol\right)\)

=> \(m_{HCl}=0,2.36,5=7,3\left(g\right)\)

Ta có: \(C_{\%_{HCl}}=\dfrac{7,3}{m_{dd_{HCl}}}.100\%=14,6\%\)
=> \(m_{dd_{HCl}}=50\left(g\right)\)

d. Ta có: \(m_{dd_{CaCl_2}}=12+50-0,1.64=55,6\left(g\right)\)

Theo PT: \(n_{CaCl_2}=n_{SO_2}=0,1\left(mol\right)\)

=> \(m_{CaCl_2}=0,1.111=11,1\left(g\right)\)

=> \(C_{\%_{CaCl_2}}=\dfrac{11,1}{55,6}.100\%=19,96\%\)

\(a)n_{H_2}=\dfrac{8,96}{22,4}=0,4mol\\ n_{Fe}=a;n_{Al}=b\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

\(\Rightarrow\left\{{}\begin{matrix}56a+27b=11\\a+1,5b=0,4\end{matrix}\right.\\ \Rightarrow a=0,1;b=0,2\)

\(\%m_{Fe}=\dfrac{0,1.56}{11}\cdot100=50,91\%\\ \%m_{Al}=100-50,91=49,09\%\)

\(b)Fe+2HCl\rightarrow FeCl_2+H_2\)

0,1            0,2          0,1          0,1

\(2Al+6HCl\rightarrow2AlCl_2+3H_2\)

0,2          0,6           0,2            0,3

\(m_{HCl}=\dfrac{\left(0,2+0,6\right).36,5}{9,125}\cdot100=320g\)       

\(c)m_{dd}=320+11-0,1.2-0,3.2=308,2g\)

\(C_{\%FeCl_2}=\dfrac{0,1.127}{308,2}\cdot100=4,12\%\\ C_{\%AlCl_3}=\dfrac{0,2.133,5}{308,2}\cdot100=8,66\%\)

\(n_{H_2}=\dfrac{3.36}{22.4}=0.15\left(mol\right)\)

\(Mg+2HCl\rightarrow MgCl_2+H_2\)

\(0.15.....0.3.......................0.15\)

\(m_{Mg}=0.15\cdot24=3.6\left(g\right)\)

\(m_{Cu}=10-3.6=6.4\left(g\right)\)

\(\%Mg=\dfrac{3.6}{10}\cdot100\%36\%\)

\(\%Cu=64\%\)

\(V_{dd_{HCl}}=\dfrac{0.3}{2}=0.15\left(l\right)\)

\(n_{H_2}=\dfrac{8,96}{22,4}=0,4mol\)

Gọi số mol Fe và Al lần lượt là: x và y

\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

x            x                  x       x

\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)

y             1,5y                               1,5y

Ta có:

\(\left\{{}\begin{matrix}56x+27y=11\\x+1,5y=0,4\end{matrix}\right.\)                \(\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)

\(\%m_{Fe}=\dfrac{0,1.56}{11}.100\%=50,9\%\)

\(\%m_{Al}=100\%-50,9\%=49,1\%\)

Đặt \(n_{Fe}=x(mol);n_{Al}=y(mol)\Rightarrow 56x+27y=11(1)\)

\(n_{H_2}=\dfrac{8,96}{22,4}=0,4(mol)\\ PTHH:Fe+H_2SO_4\to FeSO_4+H_2\\ 2Al+3H_2SO_4\to Al_2(SO_4)_3+3H_2\\ \Rightarrow x+1,5y=0,4(2)\\ (1)(2)\Rightarrow x=0,1(mol);y=0,2(mol)\\ \Rightarrow \%_{Fe}=\dfrac{0,1.56}{11}.100\%=50,91\%\\ \Rightarrow \%_{Al}=100\%-50,91\%=49,09\%\)